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BodyCenter9677375 clearfix'> <ul class="one-classify-box"> <li id="0o0iskk" class="main-class-item"> <a class="main-class-text OneRow" href="/company/" target="_self">公司新聞</a> </li> <li id="osocawo" class="main-class-item"> <a class="main-class-text OneRow" href="/industry/" target="_self">行業(yè)動(dòng)態(tài)</a> </li> </ul> <script type="text/javascript">addScript('/template/default/js/commoncls.js', function () { initCommonClsGiant(9677375,'105') });</script> </div> </div> </div> <div id="gaiwu2k" class="ModuleItem StaticModule " wo="738" id="module_9664189" > <div id="akkw0w2" class="ModuleNewsDetail module_9664189 clearfix">  <div id="weckgog" class='BodyCenter BodyCenter9664189 clearfix'> <div><h2 class="newsDetailTitle">鍋爐煙氣脫硫脫硝技術(shù)方案的比較選擇4</h2> <div id="0uuggy0" class="newsSource"> </div> <div id="womg0u0" class="NewsContent"> <p style="text-indent: 2em; text-align: left;"><p><span style="font-size:19px">4.1 </span><span style="font-size:19px;font-family:宋體">摩爾比</span></p><p><span style="font-size:19px;font-family:宋體">摩爾比（</span><span style="font-size:19px">O</span><sub><span style="font-size: 19px">3</span></sub><span style="font-size:19px">/NO</span><span style="font-size:19px;font-family:宋體">）是指</span><span style="font-size:19px">O</span><sub><span style="font-size:19px">3</span></sub><span style="font-size:19px;font-family:宋體">與</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">之間摩爾數的比值，它反映了臭氧量相對于一氧化氮量的高低。</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">的氧化率隨</span><span style="font-size:19px">O</span><sub><span style="font-size: 19px">3</span></sub><span style="font-size:19px">/NO</span><span style="font-size:19px;font-family:宋體">的升高直線(xiàn)上升。目前已有的研究中，在</span><span style="font-size:19px">0.9</span><span style="font-size:19px;font-family:宋體">≤</span><span style="font-size:19px">O</span><sub><span style="font-size: 19px">3</span></sub><span style="font-size:19px">/NO</span><span style="font-size:19px;font-family:宋體">＜</span><span style="font-size:19px">1</span><span style="font-size:19px;font-family:宋體">的情況下，脫硝率可達到</span><span style="font-size:19px">85%</span><span style="font-size:19px;font-family:宋體">以上，有的甚至幾乎達到</span><span style="font-size:19px">100%</span><span style="font-size:19px;font-family:宋體">；在實(shí)際中，由于其他物質(zhì)的干擾，可發(fā)生一系列其他反應，如式（</span><span style="font-size: 19px">2</span><span style="font-size:19px;font-family:宋體">）～（</span><span style="font-size:19px">5</span><span style="font-size:19px;font-family:宋體">），使得</span><span style="font-size:19px">O</span><sub><span style="font-size: 19px">3</span></sub><span style="font-size:19px;font-family:宋體">不能</span><span style="font-size:19px">100%</span><span style="font-size:19px;font-family:宋體">與</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">進(jìn)行反應。</span></p><p><span style="font-size:19px">4.2 </span><span style="font-size:19px;font-family:宋體">溫度</span></p><p><span style="font-size:19px;font-family:宋體">由于臭氧的生存周期關(guān)系到</span><span style="font-size:19px;font-family:宋體">脫硫脫硝</span><span style="font-size:19px;font-family:宋體">效率的高低，所以考察臭氧對溫度的敏感性具有重要意義。所有試驗都表明，臭氧所處的環(huán)境溫度越高分解越快，溫度越低分解越慢。在</span><span style="font-size:19px">150</span><span style="font-size:19px;font-family:宋體">℃</span><span style="font-size: 19px;font-family:宋體">的低溫條件下，臭氧的分解率相對較低。在</span><span style="font-size:19px">25</span><span style="font-size:19px;font-family:宋體">℃</span><span style="font-size:19px;font-family:宋體">時(shí)臭氧的分解率只有</span><span style="font-size:19px">0.5%</span><span style="font-size:19px;font-family:宋體">，臭氧的半衰期可達</span><span style="font-size: 19px">15</span><span style="font-size:19px;font-family:宋體">秒。</span></p><p><span style="font-size:19px">4.3 </span><span style="font-size:19px;font-family:宋體">反應時(shí)間</span></p><p><span style="font-size:19px;font-family:宋體">臭氧在煙氣中的停留時(shí)間只要能夠保證氧化反應的完成即可，因為關(guān)鍵反應的反應平衡在很短時(shí)間內即可達到，不需要較長(cháng)的臭氧停留時(shí)間。反應時(shí)間</span><span style="font-size:19px">1</span><span style="font-size:19px;font-family:宋體">秒足矣。據華北電力大學(xué)環(huán)境學(xué)院</span><span style="font-size:19px;font-family:宋體">馬雙忱等</span><span style="font-size:19px;font-family:宋體">人的技術(shù)文獻證實(shí)：</span><span style="font-size:19px;font-family:宋體">在1～10000秒之間，對反應器出口的NO摩爾數沒(méi)有什么影響，而且增加停留時(shí)間并不能增大NO的脫除率。</span></p><p><span style="font-size:19px">5</span><span style="font-size:19px;font-family:宋體">、</span> <span style="font-size:19px;font-family:宋體">臭氧氧化技術(shù)的工程應用</span></p><p><span style="font-size:19px">C</span><span style="font-size:19px;font-family:宋體">—</span><span style="font-size:19px">GT<sub>X</sub></span><span style="font-size:19px;font-family:宋體">是一種低溫氧化技術(shù)，將氧</span><span style="font-size:19px">/</span><span style="font-size:19px;font-family:宋體">臭氧混合氣注入再生器煙道，將</span><span style="font-size:19px">NO</span><sub><span style="font-size: 19px">X</span></sub><span style="font-size:19px;font-family:宋體">氧化成高價(jià)態(tài)且易溶于水的</span><span style="font-size:19px">NO</span><sub><span style="font-size: 19px">2</span></sub><span style="font-size:19px;font-family:宋體">和</span><span style="font-size:19px">N</span><sub><span style="font-size: 19px">2</span></sub><span style="font-size:19px">O</span><sub><span style="font-size:19px">5</span></sub><span style="font-size:19px;font-family:宋體">，然后通過(guò)氨水洗滌并使其與氨水反應生成硝酸鹽，或與水反應還原氮氣。</span></p><p><span style="font-size:19px;font-family:宋體">主要的反應如下：</span></p><p><span style="font-size:19px">NO+O</span><sub><span style="font-size:19px">3</span></sub><span style="font-size:19px;font-family:宋體">→</span><span style="font-size:19px">NO</span><sub><span style="font-size:19px">2</span></sub><span style="font-size: 19px">+O</span><sub><span style="font-size:19px">2</span></sub><span style="font-size:19px"> </span><span style="font-size:19px;font-family:宋體">（</span><span style="font-size:19px">6</span><span style="font-size:19px;font-family:宋體">）</span></p><p><span style="font-size:19px">2NO</span><sub><span style="font-size:19px">2</span></sub><span style="font-size: 19px">+O</span><sub><span style="font-size:19px">3</span></sub><span style="font-size:19px;font-family:宋體">→</span><span style="font-size:19px">N</span><sub><span style="font-size:19px">2</span></sub><span style="font-size: 19px">O</span><sub><span style="font-size:19px">5</span></sub><span style="font-size:19px">+O</span><sub><span style="font-size: 19px">2</span></sub> <span style="font-size:19px"> </span><span style="font-size:19px;font-family:宋體">（</span><span style="font-size:19px">7</span><span style="font-size:19px;font-family:宋體">）</span></p><p><span style="font-size:19px">N</span><sub><span style="font-size:19px">2</span></sub><span style="font-size: 19px">O</span><sub><span style="font-size:19px">5</span></sub><span style="font-size:19px">+H</span><sub><span style="font-size: 19px">2</span></sub><span style="font-size:19px">O</span><span style="font-size:19px;font-family:宋體">→</span><span style="font-size:19px">2HNO</span><sub><span style="font-size:19px">3</span></sub> <span style="font-size:19px"> </span><span style="font-size:19px;font-family:宋體">（</span><span style="font-size:19px">8</span><span style="font-size:19px;font-family:宋體">）</span></p><p><span style="font-size:19px">4NH<sub>3</sub> + 2NO<sub>2</sub> + O<sub>2</sub> </span><span style="font-size:19px;font-family:宋體">→</span><span style="font-size:19px">6H<sub>2</sub>O + 3N<sub>2</sub> </span><span style="font-size:19px;font-family:宋體">（</span><span style="font-size:19px">9</span><span style="font-size:19px;font-family:宋體">）</span></p><p><span style="font-size:19px">4NO<sub>2</sub>+ 4NH<sub>3</sub>?H<sub>2</sub>O+O<sub>2</sub> </span><span style="font-size:19px;font-family:宋體">→</span><span style="font-size:19px">4NH<sub>4</sub>NO<sub>3</sub> + 2H<sub>2</sub>O </span><span style="font-size:19px;font-family:宋體">（</span><span style="font-size:19px">10</span><span style="font-size:19px;font-family:宋體">）</span></p><p style="margin-left:48px"><strong><span style="font-size:19px">一、<span style="font-variant-numeric: normal;font-weight: normal;font-stretch: normal;font-size: 9px;line-height: normal;font-family: 'Times New Roman'"> </span></span></strong><strong><span style="font-size:19px">AC-GTsx</span></strong><strong><span style="font-size:19px;font-family:宋體">系統工藝流程</span></strong></p><p style="margin-left:48px"><span style="font-size: 19px;font-family:宋體">1、<span style="font-variant-numeric: normal;font-stretch: normal;font-size: 9px;line-height: normal;font-family: 'Times New Roman'"> </span></span> </p><table cellpadding="0" cellspacing="0"><tbody><tr class="firstRow"><td width="136" height="35" bgcolor="white" style="vertical-align:top;background: white"><span style="position:absolute;left:0;z-index:251657728"> 潔凈煙氣排放</span> </td></tr></tbody></table><p><span style="font-size:19px;font-family:宋體">A</span><span style="font-size:19px">C</span><span style="font-size:19px;font-family:宋體">—</span><span style="font-size:19px">GT<sub>SX</sub></span><span style="font-size:19px;font-family:宋體">系統工藝流程圖</span></p><p><br/></p><p><span style="font-size:19px"><span style=";position:absolute;z-index:0;margin-left:168px;margin-top:168px;width:40px;height:77px"><img width="40" height="77" src="http://www.roukuan.cn/yqj2013/ueditor/themes/default/images/spacer.gif" alt="文本框: 臭氧發(fā)生器" word_img="file:///C:/Users/ADMINI~1/AppData/Local/Temp/msohtmlclip1/01/clip_image009.gif" style="background:url(http://www.roukuan.cn/yqj2013/ueditor/themes/default/images/word.gif) no-repeat center center;border:1px solid #ddd"/></span><span style=";position:absolute;z-index:0;margin-left:408px;margin-top:127px;width:40px;height:149px"><br/></span></span></p><p style="text-align: center;"><span style="font-size:19px"> <img src="/upload/image/20190404/15543627707152037.jpg" title="QQ截圖20190404152425.jpg" alt="QQ截圖20190404152425.jpg"/></span></p><p><span style="font-size:19px">2</span><span style="font-size:19px;font-family:宋體">、</span><span style="font-size:19px;font-family:宋體">A</span><span style="font-size:19px">C</span><span style="font-size:19px;font-family:宋體">—</span><span style="font-size:19px">GT<sub>SX</sub></span><span style="font-size:19px;font-family:宋體">工藝流程技術(shù)說(shuō)明</span></p><p><span style=";font-family:宋體">（</span><span style="font-size:19px;font-family:宋體">參閱《</span><span style="font-size: 19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">系統工藝流程圖》）本氨水</span><span style="font-size:19px">-</span><span style="font-size:19px;font-family:宋體">臭氧</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">系統設立在引風(fēng)機出風(fēng)口與煙囪進(jìn)風(fēng)口之間。電除塵后的煙氣經(jīng)引風(fēng)機被送</span><span style="font-size:19px;font-family:宋體">入AC—GT<sub>SX</sub></span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">塔的進(jìn)風(fēng)口，煙氣在</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">塔內由下而上首先進(jìn)入氨水噴淋脫硫凈化區，經(jīng)氨水（脫硫劑）多層循環(huán)噴淋后，</span><span style="font-size:19px">90%</span><span style="font-size:19px;font-family:宋體">以上的硫化有毒氣體和</span><span style="font-size:19px">NO<sub>2</sub></span><span style="font-size:19px;font-family:宋體">氣體在此凈化區將被脫除。同時(shí)還會(huì )有</span><span style="font-size:19px">10%</span><span style="font-size:19px;font-family:宋體">左右的</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">氣體也會(huì )被脫除掉，這主要是由于脫硫液在循環(huán)脫硫時(shí)會(huì )產(chǎn)生一部分</span><span style="font-size:19px">NH<sub>4</sub>HSO<sub>3</sub></span><span style="font-size:19px;font-family:宋體">。這種化合物能溶于水中，在循環(huán)噴淋過(guò)程中，雖然失去了對</span><span style="font-size:19px">SO<sub>2</sub></span><span style="font-size:19px;font-family:宋體">的吸附能力，但對</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">卻有很強的吸附作用，它吸附</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">后生成</span><span style="font-size:19px">(NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub></span><span style="font-size: 19px;font-family:宋體">和</span><span style="font-size:19px">H<sub>2</sub>SO<sub>3</sub></span><span style="font-size:19px;font-family:宋體">，還原氮氣。</span><span style="font-size:19px;font-family:宋體">在噴淋凈化塔內煙氣經(jīng)過(guò)基本脫硫、脫塵和部分脫硝后繼續向上進(jìn)入脫硝凈化區。在這一區段內，煙氣中的</span><span style="font-size:19px">NO</span><span style="font-size:19px;font-family:宋體">被</span><span style="font-size:19px">O3</span><span style="font-size:19px;font-family:宋體">快速氧化成</span><span style="font-size:19px;font-family:宋體">易溶于水的</span><span style="font-size: 19px">NO</span><sub><span style="font-size:19px">2</span></sub><span style="font-size:19px;font-family:宋體">、</span><span style="font-size:19px">N</span><sub><span style="font-size:19px">2</span></sub><span style="font-size: 19px">O</span><sub><span style="font-size:19px">3</span></sub><span style="font-size:19px;font-family:宋體">、</span><span style="font-size:19px">N</span><sub><span style="font-size:19px">2</span></sub><span style="font-size: 19px">O</span><sub><span style="font-size:19px">5</span></sub><span style="font-size:19px;font-family:宋體">等高價(jià)態(tài)氮氧化物。受?chē)娏芤旱陌彼饔冒l(fā)生化學(xué)反應生成</span><span style="font-size:19px">NH<sub>4</sub>NO<sub>3</sub></span><span style="font-size:19px;font-family:宋體">和水</span><span style="font-size:19px;font-family:宋體">；或受?chē)娏芤褐械乃淖饔蒙伤?，還原氮氣。煙氣經(jīng)脫硝后進(jìn)入除霧區，經(jīng)除霧器除去煙氣中大于</span><span style="font-size:19px">μm</span><span style="font-size: 19px;font-family:宋體">的霧粒，使煙氣中的水分含量達到</span><span style="font-size:19px">%</span><span style="font-size: 19px;font-family:宋體">以下，經(jīng)除霧脫水后的潔凈煙氣直接進(jìn)入煙囪，排入大氣。因</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">生成的硫酸胺和硝酸胺會(huì )因密度大而沉于</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">塔的底部，為防止塔底結垢設置攪拌泵進(jìn)行攪拌，當塔底的硫酸胺和硝酸胺溶液濃度達到一定數值時(shí)，自動(dòng)控制系統將會(huì )啟動(dòng)硫酸胺溶液排出泵將硫酸胺和硝酸胺溶液及時(shí)排出，直到</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">塔底部循環(huán)液中的硫酸胺濃度接近或達到*小控制值時(shí)，自動(dòng)控制系統就會(huì )及時(shí)將硫酸胺溶液排出泵停機。自動(dòng)控制系統還具有使工藝水箱中的水面、</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">塔中的循環(huán)液面始終保持一個(gè)相對穩定的高度，還能根據</span><span style="font-size:19px">SO<sub>2</sub></span><span style="font-size:19px;font-family:宋體">、</span><span style="font-size:19px">NO</span><span style="font-size: 19px;font-family:宋體">的在線(xiàn)檢測信息自動(dòng)調節循環(huán)液中的氨水濃度，始終保持</span><span style="font-size:19px">AC-GTsx</span><span style="font-size:19px;font-family:宋體">系統出口煙氣的</span><span style="font-size:19px">SO2</span><span style="font-size: 19px;font-family:宋體">、</span><span style="font-size: 19px">NO</span><span style="font-size: 19px;font-family:宋體">濃度低于環(huán)保部門(mén)提出的控制指標。</span></p><p><br/></p></p> </div> <br> <div id="mqcyscw" class="syp"><span id="uso000w" class="fl"> 上一篇：<a href="/industry/14.html">鍋爐煙氣脫硫脫硝技術(shù)方案的比較選擇3</a> </span><span id="ecaki0q" class="fr"> 下一篇：<a href="/industry/16.html">鍋爐煙氣脫硫脫硝技術(shù)方案的比較選擇5</a> </span></div> </div> <script>$('.NewsContent img:eq(0)').clone().hide().prependTo('body'); changeFontSize($('#module_9664189'));</script> </div> </div> </div> </div> <div id="eucc2mu" class='clearfix visible-lg'> </div> <div id="eyuqagm" class='clearfix visible-md'> </div> <div id="emkygyc" class='clearfix visible-sm'> </div> <div id="y2i0mko" class='clearfix 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